Nitrogen based flame retardants

Three chemical groups can be distinguished: pure melamine, melamine derivatives, i.e. salts with organic or inorganic acids such as boric acid, cyanuric acid, phosphoric acid or pyro/poly-phosphoric acid, and melamine homologues such as melam, melem and melon, the latter finding only experimental use at this stage. Nitrogen flame retardants are believed to act by several mechanisms: In the condensed phase, melamine is transformed into cross-linked structures which promote char formation. Ammonia is released in these reactions. In conjunction with phosphorus, the nitrogen appears to enhance the attachment of the phosphorus to the polymer. A mechanism in the gas phase may be the release of molecular nitrogen which dilutes the volatile polymer decomposition products.

Melamine is mainly used in polyurethane foams, whereas melamine cyanurate is used in nylons or in polypropylene intumescent formulations in conjunction with ammonium polyphosphate. The phosphate, poly- and pyrophosphates of melamine contain both nitrogen and phosphorus and are used in nylons. In some specific formulations, triazines, isocyanurates, urea, guanidine and cyanuric acid derivatives are used as reactive compounds.