What are PIN Flame Retardants

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Flame retardants (FRs) are included into materials to protect them from fire. They can prevent fire starting (inhibit ignition), slow fire development, protect materials from heat damage and reduce smoke emission in fires.

PIN FRs are non-halogenated and are based on the elements phosphorus and nitrogen as well as inorganic materials. They can be chemically reacted, blended, pressure impregnated or used in paints or coatings. They are used to protect synthetic materials (plastics, composites), fibres, natural materials such as wood, and also to protect structural materials against heat (steel, concrete …). While some halogenated phosphorus compounds are used as flame retardants, these are not within the scope of pinfa.

The chemical structures, properties and applications of PIN FRs are summarised below. They are here grouped under Phosphorus, Nitrogen and Inorganic, but many PIN FRs combine two or three of these components. Combinations of PIN FRs are also often used to bring synergies between their different fire protective and smoke suppressant properties.

Phosphorus PIN flame retardants

Inorganic PIN flame retardants

Nitrogen PIN flame retardants

How do PIN flame retardants work ?

PIN flame retardants (FRs) can have one or several modes of action:

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Gas phase

Counteract the reactive OH* and H* radicals which are released by materials under heat and which feed fire.

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Heat buffer

Endothermic degradation reactions absorb heat energy.

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Pyrolysis

Catalysis generating poorly flammable molecules.

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Solid phase

Generate a char lor ceramic layer on the material surface. This protects the material from fire and reduces smoke and gas emissions.

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Dispersion

Release of non-combustible gases (e.g. water, nitrogen), which dilute fire gases and oxygen.

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Smoke suppression

Various mechanisms including catalysis of cross-linking in materials or of a surface protective barrier to reduce the release of smoke and soot, and catalysis action in smoke gases.

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