Biobased, hyperbranched PIN FR

Biobased, hyperbranched PIN FR

Biobased itaconic anhydride (ITA), combined with DOPO, generated a polymeric P FR showed to be effective in epoxy. ITA is a dicarboxylic acid, derived from citric acid, which can be produced from renewable sources. It was here combined with DOPO* to generate a...
DOPO as a reactive PIN FR for epoxy

DOPO as a reactive PIN FR for epoxy

Two phosphorus compounds (DOPO, BICP) combine to cure epoxy, resulting in fire resistance and reduced smoke. DOPO (9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) and BICP (cyclotriphosphazene-modified benzimidazole) together showed to act as a curing agent for...
Bio-based PIN FR for wood fibre materials

Bio-based PIN FR for wood fibre materials

Wheat starch modified with P and N showed to be an effective FR for wood fibres and industrially processable. Wood fibres are widely used in heat and sound insulation materials, and are recyclable, compostable and non-toxic, but are flammable. Industrial wheat starch...
Complexity of neurodevelopmental toxicity assessment.

Complexity of neurodevelopmental toxicity assessment.

Fifteen brominated, chlorinated or phosphate ester flame retardants were tested using a battery of 22 different in vitro neurodevelopmental endpoint tests. Only one FR (TCIPP) showed no effect in all tests. The others showed effects in one or several tests, at...
Complexity of neurodevelopmental toxicity assessment.

Degradation products of TPP (TPHP).

Degradation of the phosphate ester FR triphenyl phosphate (generally abbreviated as TPP, here as TPHP) were studied in experiments with green microalgae, invertebrates and fish, at exposure 100 µg/l (below the NOEC). 29 biotransformation products were identified, in...