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September 7, 2023

PIN FRs and Recycling

Several presentations and posters at FRPM addressed recycling.

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Pinfa young researcher presentation awards

These pinfa Awards are the first time such prizes have been offered for presentations at FRPM. A total of 14 candidate oral presentations by young researchers were graded for scientific content, presentation quality and oral delivery by experts from fire research and industry.

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Comparing coated and impregnated FRs in plywood

Iben Hansen-Bruhn, Aarhus University, Denmark, and University of Central Lancashire, UK - Two different ammonium phosphate based PIN flame retardants were applied to 12 mm pine plywood.

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Posters Awards

Poster and Travel Awards were offered for the first time at FRPM, by the Ingeborg Foundation Germany, for posters from young researchers (51 candidate posters).

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Recycling PIN FR PET fibres

Jiuke Chen, Empa - Extruded PET (polyethylene terephthalate) fibres neat or with two different phosphorus PIN FRs (DOPO derivate DOPO-PEPA, phosphonate compound) were tested for mechanical recycling, with twin-screw extrusion – quench – spin-melt – reprocessing cycles (without ageing, total 3 extrusions).

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Computer modelling to propose safer FRs

Hannah Flerlage and Steven Beijer, University of Amsterdam - SSbD (Safe and Sustainable by Design) is applied to redesign P FR for reduced environmental hazard using a computer-based approach, starting from the existing PIN phosphorus flame retardant Tri-iso-butyl phosphate (TiBP).

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Bio-based intumescent PIN FR coating for NYCO

Nathalie Vest, Texas A&M University - Nylon-cotton fabric (NYCO) was multi-layer coated with phytic acid, chitosan and tannic acid, achieving self-extinguishing with 17% weight added. NYCO is widely used in military uniforms and workwear, but has high flammability because of interaction between the two fibres in fire.

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Polymeric PIN FR for PLA

Marie-Odile Augé, Centrale Lille France - A self-polymerising commercial additive was compounded into poly lactic acid (PLA) using a twin-screw extruder operating at 185°C.

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Bio-derived PIN FRs for cotton

Alessandro Beduini, University of Milan. Polyamidoamines, synthesised from a bisacrylamide (MBA) and natural amino acids, soaked into cotton, significantly improved fire performance.

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Analysing gas phase action of different PIN FRs

Daniela Goedderz, Fraunhofer IBF. Action of the modes of action of PIN flame retardants, gas transport, flame topology and gaseous pyrolysis products, by a combination of optical diagnostics (planar laser-induced fluorescence spectroscopy of OH-radicals) and pyrolysis fragment analysis (TGA-FTIR).

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June 27, 2023

Call to add P to Strategic Raw Materials List

pinfa calls for phosphorus to be identified as crucial for fire safety for all of the identified EU “Strategic” industries: batteries, renewable energy, electrical systems, circuit boards, electronic, power and data cables, aerospace.

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Call for flame retardants book contributions

Industry expert input is invited for new Elsevier book on “Flame Retardant Selection for Polymers”, covering FR selection, formulation and regulations.

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EU public consultation on Polluter Pays

Open to 4th August 2023 HERE. Further information see pinfa Newsletter n°149

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UNEP reports on chemicals in plastics

Document for UN Plastics Treaty on plastics identifies certain specific flame retardants as one of ten chemical concerns.

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Washington State FR restrictions

Ban of all halogenated FRs in E&E casings and of halogenated FRs and five phosphorus FRs in some polyurethane foams.

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Electronics industry position on FRs

DIGITALEUROPE says FRs “provide essential fire protection” and prefer RoHS to REACH for regulation of FRs in electronics.

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Questioning phosphorus FR toxicity

Discussions article by polymer chemicals researcher suggests effective phosphorus flame retardants may have low toxicity.

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Fire safety crucial for energy storage

Industry experts say US will need 100 GW of battery grid storage by 2030 and fire safety is needed to enable this.

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Virtual reality for fire awareness

US Fire Administration, FEMA and META, launch virtual reality experience tool to promote fire safety awareness.

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PIN flame retardant resin for 3D-printing

Formlabs’ new non-halogenated performance resin achieves UL 94 V-0, is self-extinguishing, low smoke and low toxicity, enabling 3D-printing of performance components for aviation, railway and other transport applications, E&E, industrial parts, etc.

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Performance PIN masterbatch for PE foams

Tosaf launches new phosphorus flame retardant for polyethylene foams for insulation, packaging, construction.

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Durability of flame retardant materials

Expert review notes progress in FR durability over time, but research is needed on outdoor durability and recycling.

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PIN FRs for recycled newspaper composite

PIN flame retardants were tested to enable fire safety of polypropylene – recycled newspaper fibre composites.

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Biobased phosphorus – magnesium PIN FR

Magnesium hydroxide – phytic acid compound improved fire performance and reduced smoke loss in polyethylene.

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