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May 28, 2021

Low-smoke, halogen-free polyolefin cable

Benvic, a world leader in PVC compounds, has launched HFFR polyolefin cables for construction and electrical industries. The new LINKFLEX HF compounds for cables and sheathing ensure compliance with the EU Construction Product Regulations (CPR) EN 50575 Eca up to B2ca, with low droplets, using PIN flame retardants in a polyolefin matrix to ensure low smoke properties, IEC 60754-2 low acidity emissions.

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WAPOL: PIN FRs from waste materials

EU project develops PIN FR compounds using waste incineration ash and nitrogen FRs for PP, PA (polypropylene, polyamide). The Horizon 2020 (EIT Raw Materials) project, WAPOL, is developing flame retarded polymers for the automotive industries using PIN FRs from waste materials. PP filled with 20-30% municipal waste incineration ash (treated bottom ash) achieved UL94HB @ 1.6 mm with mechanical properties similar to those of PP-T20.

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Performance PC/ABS and PC/ASA

Polymer Compounders Ltd (PCL) new polycarbonate blend compounds show excellent properties and low toxicity. Established in 1993, PCL specialises in engineering thermoplastics. Their new PC/ABS* and PC/ASA* blends claim better melt processing, lower density and physical properties as good as halogen FR compounds, but use reactive non-halogenated FR polymer formulations to ensure a favourable toxicity profile, no antimony, no FR migration and no bioaccumulation.

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Metal alginates as PIN flame retardants

Alginates loaded with metal ions can provide effective bio-based PIN FRs for textiles, polymers, surface coatings …. Tens of thousands of tonnes of alginates are produced worldwide annually from brown algae, providing relatively low-cost bio-based materials which are not competing with food crops.

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Bio-based PIN FR for cotton

The natural molecule polylysine, reacted with phosphoric acid, provides a durable PIN FR for cotton fabrics. The polypeptide ε polylysine can be produced by natural fermentation or by a condensation reaction of the biological amino acid lysine, and is used as a food additive.

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“Green” synthesis of PIN FR for bioplastic

Researchers propose solvent-free synthesis of polymeric phosphorus FR for poly(lactic acid) bioplastic (PLA). The bio-based and biodegradable polymer poly(lactic acid) is highly flammable. Phosphoramides have shown to be effective PIN FRs for PLA at low loadings, but their synthesis relies on organic solvents.

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Double FR functionality of phosphorus

An experimental P-based PIN FR for rigid polyurethane foam shows both gas phase and solid phase fire inhibition effects. Researchers synthesised (in two steps) a bi-functional, reactive phosphorus flame retardant for rigid polyurethane foam: PDEP, containing a DOPO and a phosphate (DEP, derived from diethyl phosphite).

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N-P-Si FR for epoxy

Experimental reactive PIN FR improves mechanical and fire performance of epoxy resin. DOPO (phosphorus) and triethylamine (nitrogen) were reacted with silane (silicon) to generate an N-P-phenylsiloxane macromolecule (PD-PPD) which could be reacted into DGEBA epoxy resin.

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UK consults on POP ban for Dechlorane Plus.

UK consults on POP ban for Dechlorane Plus. The UK Government has opened to 18th June 2021 a public consultation on adding the halogenated flame retardant Dechlorane Plus to the Stockholm Convention list of Persistent Organic Pollutants.

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April 30, 2021

Other news

Endocrine (EDC) effects of “replacement” FRs. Experimental data and endocrine modelling results were collected for 52 flame retardants considered to be possible replacement of brominated PBDE and HBCD FRs.

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New tool to teach fire safety and FRs

80+ slides of information and graphics explaining materials fire safety, flame retardants, fire tests, standards, environment and health.

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US EPA consultation on Deca, HBCD, TIPPP

Public comment is requested on rules to reduce exposure to PBT chemicals including three FRs: Deca-BDE, HBCD, TIPPP.

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Unlimited fines for fire safety regulations

The UK Government has announced unlimited fines for breaching fire safety orders or obstructing fire inspectors.

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Sustainable Products Initiative consultation

EU public consultation to 9th June 2021 on the Sustainable Products Initiative, targeting mainly recycling and reuse.

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Review on flame retarding of batteries

Fire and thermal runaway risks of lithium ion batteries can be reduced by using PIN FRs in separators, electrolyte, cathode.

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Review on fire safety of battery separators

Flame retardant separators are important to prevent or limit lithium ion battery fires and thermal runaway.

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Full-scale fire test of EV battery

In just 22 seconds, cell thermal runaway spreads flames throughout the battery compartment. A full-scale fire test was carried out on a battery system of seventeen 3P6S battery modules mounted with control systems in a car chassis.

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Efectis report on battery fires

Report to EU underlines fire safety problems of lithium ion batteries, incidents in uses from electronics to airplanes.

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PIN FR polyamide PA6 for 3D-printing

BASF FORWARD AM offers a non-halogenated FR PA6 for 3D-printing of performance parts for public transport and electronics.

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Graphite PIN FR for railways

Tirupti Graphite has a first order for non-halogenated FR polyurethane foam and composite for railway carriages.

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Developing PIN FR for expanded foam parts

Unipetrol is working on low-migration, halogen- and antimony-free fire safety in lightweight automotive foamed parts.

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Thermally conductive epoxy resins for LEDs

PIN FRs enable fire performance, low smoke and fumes, transparency and thermal conductivity for LEDs. Electrolube, a global formulated chemical supplier since 1941 to electronics and industry, has developed innovative thermally conductive flame retardant epoxy resins.

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Rubber flooring for rail fire safety

Treadmaster PIN FR flooring offers fire safety beyond standard rail requirements, wear resistance and visual appeal.

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Performance FR cables for solar PV

Cicoil low-smoke, zero-halogen FR cables for reliable, weather and UV resistant performance in solar and technical uses.

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